We know Aluminium is more reactive than Iron.
So it reacts faster with the oxygen in the air forming Aluminium oxide,
Aluminium oxide is very unreactive , because once the oxide layer forms on the aluminium surface , it binds very tightly to the surface of the Aluminium , so no cracks can form that cause further corrosion.
This idea is used to prevent the Iron from corrosion by covering it with a thin layer of less reactive metal.
This process of covering of metal is known as Galvanizing.
;)
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